9.7.4 Responses to Specific Hazards

Class 1 (Explosives)

If your vehicle has a breakdown or accident while carrying explosives, warn others of the danger. Keep bystanders away. Do not allow smoking or open fire near the vehicle. If there is a fire, warn everyone of the danger of explosion.

Remove all explosives before separating vehi­cles involved in a collision. Place the explosives at least 200 feet from the vehicles and occupied buildings. Stay a safe distance away.

Class 2 (Compressed Gases)

If compressed gas is leaking from your vehicle, warn others of the danger. Only permit those involved in removing the hazard or wreckage to get close. You must notify the shipper if compressed gas is involved in any accident.

Unless you are fueling machinery used in road construction or maintenance, do not transfer a flammable compressed gas from one tank to another on any public roadway.

Class 3 (Flammable Liquids)

If you are transporting a flammable liquid and have an accident or your vehicle breaks down, prevent bystanders from gathering. Warn people of the danger. Keep them from smoking.

Never transport a leaking cargo tank farther than needed to reach a safe place. Get off the roadway if you can do so safely. Don't transfer flammable liquid from one vehicle to another on a public roadway except in an emergency.

Class 4 (Flammable Solids) and Class 5 (Oxidizing Materials)

If a flammable solid or oxidizing material spills, warn others of the fire hazard. Do not open smoldering packages of flammable solids. Remove them from the vehicle if you can safely do so. Also, remove unbroken packages if it will decrease the fire hazard.

Class 6 (Poisonous Materials and Infectious Substances)

It is your job to protect yourself, other people, and property from harm. Remember that many products classed as poison are also flammable. If you think a Division 2.3 (Poison Gases) or Division 6.1 (Poison Materials) might be flammable, take the added precautions needed for flammable liquids or gases. Do not allow smoking, open flame, or welding. Warn others of the hazards of fire, of inhaling vapors, or coming in contact with the poison.

A vehicle involved in a leak of Division 2.3 (Poison Gases) or Division 6.1 (Poisons) must be checked for stray poison before being used again.

If a Division 6.2 (Infectious Substances) package is damaged in handling or transportation, you should immediately contact your super­visor. Packages that appear to be damaged or show signs of leakage should not be accepted.

Class 7 (Radioactive Materials)

If radioac­tive material is involved in a leak or broken package, tell your dispatcher or supervisor as soon as possible. If there is a spill, or if an internal container might be damaged, do not touch or inhale the material. Do not use the vehicle until it is cleaned and checked with a survey meter.

Class 8 (Corrosive Materials)

If corrosives spill or leak during transportation, be careful to avoid further damage or injury when handling the containers. Parts of the vehicle exposed to a corrosive liquid must be thoroughly washed with water. After unloading, wash out the inte­rior as soon as possible before reloading.

If continuing to transport a leaking tank would be unsafe, get off the road. If safe to do so, contain any liquid leaking from the vehicle. Keep bystanders away from the liquid and its fumes. Do everything possible to prevent injury to yourself and to others.

9.7.5 Required Notification

The National Response Center helps coordinate emergency response to chemical hazards. It is a resource to the police and firefighters. It maintains a 24-hour toll-free line (phone: 800 424 8802). You or your employer must phone when any of the following occur as a direct result of a hazardous materials incident:

  • A person is killed.
  • An injured person requires hospitalization.
  • Estimated property damage exceeds $50,000.
  • The general public is evacuated for more than one hour.
  • One or more major transportation arteries or facilities are closed for one hour or more.
  • Fire, breakage, spillage, or suspected radioactive contamination occurs.
  • Fire, breakage, spillage or suspected contami­nation occur involving shipment of etiologic agents (bacteria or toxins).
  • A situation exists of such a nature (e.g., continuing danger to life exists at the scene of an incident) that, in the judgment of the carrier, should be reported.

National Response Center

(800) 424-8802

Persons telephoning the National Response Center should be ready to give:

  • Their name.
  • Name and address of the carrier they work for.
  • Phone number where they can be reached.
  • Date, time, and location of incident.
  • The extent of injuries, if any.
  • Classification, name, and quantity of hazardous materials involved, if such information is available.
  • Type of incident and nature of hazardous materials involvement and whether a continuing danger to life exists at the scene.

If a reportable quantity of hazardous sub­stance was involved, the caller should give the name of the shipper and the quantity of the hazardous substance discharged.

Be prepared to give your employer the required information as well. Carriers must make detailed written reports within 30 days of an incident.

CHEMTREC

(800) 424-9300

The Chemical Transportation Emergency Center (CHEMTREC) in Washington also has a 24-hour toll-free line. CHEMTREC was created to provide emergency personnel with technical information about the physical properties of hazardous materials. The National Response Center and CHEMTREC are in close communication. If you call either one, they will tell the other about the problem when appropriate. Do not leave radioactive yellow - II or yellow - III labeled packages near people, animals, or film longer than shown in Figure 9.10.

Figure 9.10a: Radioactive Separation for Minimum Distance in Feet to Nearest Undeveloped Film - Table A
Total Transport Index 0 to 2 hours 2 to 4 hours 4 to 8 hours 8 to 12 hours Over 12 hours
None 0 feet 0 feet 0 feet 0 feet 0 feet
0.1 to 1 1 feet 2 feet 3 feet 4 feet 5 feet
1.1 to 5.0 3 feet 4 feet 6 feet 8 feet 11 feet
5.1 to 10.0 4 feet 6 feet 9 feet 11 feet 15 feet
10.1 to 20.0 5 feet 8 feet 12 feet 16 feet 22 feet
20.1 to 30.0 7 feet 10 feet 15 feet 20 feet 29 feet
30.1 to 40.0 8 feet 11 feet 17 feet 22 feet 33 feet
40.1 to 50.0 9 feet 12 feet 19 feet 24 feet 36 feet

 

Figure 9.10b: Radioactive Separation to People Or Cargo Compartment Partitions - Table A
Total Transport Index Distance to People or Cargo Compartment Partitions
None 0 feet
0.1 to 1 1 feet
1.1 to 5.0 2 feet
5.1 to 10.0 3 feet
10.1 to 20. 4 feet
20.1 to 30.0 5 feet
30.1 to 40.0 6 feet
40.1 to 50.0 Not Applicable


Classes of Hazardous Materials

Hazard­ous materials are categorized into nine major hazard classes and additional categories for consumer commodities and combustible liquids. The classes of hazardous materials are listed in Figure 9.11.

Hazard Class Definitions - Table B
Class Class Name Example
1 Explosives Ammunition, Dynamite, Fireworks
2 Gases Propane, Oxygen, Helium
3 Flammable Gasoline Fuel, Acetone
4 Flammable Solids Matches, Fuses
5 Oxidizers Ammonium Nitrate, Hydrogen Peroxide
6 Poisons Pesticides, Arsenic
7 Radioactive Uranium, Plutonium
8 Corrosives Hydrochloric Acid, Battery Acid
9 Miscellaneous Hazardous Materials Formaldehyde, Asbestos
None ORM-D
(Other Regulated Material-Domestic)
Hair Spray or Charcoal
None Combustible Liquids Fuel Oils, Lighter Fluid

 

Test Your Knowledge - Subsections 9.6 and 9.7

  • If your placarded trailer has dual tires, how often should you check the tires?
  • What is a safe haven?
  • How close to the traveled part of the roadway can you park with Division 1.2 or 1.3 materials?
  • How close can you park to a bridge, tunnel, or building with the same load?
  • What type of fire extinguisher must placarded vehicles carry?
  • You're hauling 100 pounds of Division 4.3 (dangerous when wet) materials. Do you need to stop before a railroad-highway crossing?
  • At a rest area you discover your hazardous materials shipments slowly leaking from the vehicle. There is no phone around. What should you do?
  • What is the Emergency Response Guide (ERG)?

These questions may be on your test. If you can't answer them all, re-read subsections 9.6 and 9.7.